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Record #88543:

Kinetics of the BrO+ClO reaction and implications for stratospheric ozone / Alan J. Hills, Ralph J. Cicerone, Jack G. Calvert, John W. Birks.

Title: Kinetics of the BrO+ClO reaction and implications for stratospheric ozone / Alan J. Hills, Ralph J. Cicerone, Jack G. Calvert, John W. Birks.
Author(s): Hills, Alan J.
Cicerone, Ralph J.
Calvert, Jack G.
Birks, John W.
Date: 1987.
In: Nature. (1987.), Vol. 328(6129) (1987)
Abstract: Major uncertainty in theories that this reaction is contributing factor to losses of ozone over Antarctica in spring has been rate constant and product distribution of reaction as function of temperature. First direct measurements of these parameters are now reported, and it is shown that this reaction could account for large fraction of ozone depletion and provide source of chlorine dioxide of sufficient size to explain recent measurements in Antarctic stratosphere, provided that stratosphere contains enough bromine.
Notes:

Nature. Vol. 328(6129) :405-408 (1987).

Keywords: 551.510.534 -- Ozone layer.
551.510.41 -- Atmosphere, chemical properties.
D -- Atmospheric sciences.
(*7) -- Antarctic regions.
SPRI record no.: 88543

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245 00 ‡aKinetics of the BrO+ClO reaction and implications for stratospheric ozone /‡cAlan J. Hills, Ralph J. Cicerone, Jack G. Calvert, John W. Birks.
260 ## ‡a[S.l.] :‡b[s.n.],‡c1987.
300 ## ‡ap. 405-408 :‡bdiags., tables.
500 ## ‡aNature. Vol. 328(6129) :405-408 (1987).
520 3# ‡aMajor uncertainty in theories that this reaction is contributing factor to losses of ozone over Antarctica in spring has been rate constant and product distribution of reaction as function of temperature. First direct measurements of these parameters are now reported, and it is shown that this reaction could account for large fraction of ozone depletion and provide source of chlorine dioxide of sufficient size to explain recent measurements in Antarctic stratosphere, provided that stratosphere contains enough bromine.
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650 07 ‡a551.510.41 -- Atmosphere, chemical properties.‡2udc
650 07 ‡aD -- Atmospheric sciences.‡2local
651 #7 ‡a(*7) -- Antarctic regions.‡2udc
700 1# ‡aHills, Alan J.
700 1# ‡aCicerone, Ralph J.
700 1# ‡aCalvert, Jack G.
700 1# ‡aBirks, John W.
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